Morandi Lab @morandilab Twitter profile

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Morandi Lab

@morandilab

2 years

Ever wondered about directly turning the indole skeleton of a bioactive compound into a quinazoline or quinoxaline by "just" inserting a N atom? Check this MS @ChemRxiv from Julia, @origree1 , @HappyFranchino , @PDFinkelstein .

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Morandi Lab

@morandilab

2 years

We are looking for PhD students - starting date open. See details below, retweet appreciated😀. Applications to: morandi.phd @gmail .com

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Morandi Lab

@morandilab

3 years

Congrats to Yong Ho and Elliott! Now out in @NatureChemistry , previously on @ChemRxiv . Palladium-catalysed carboformylation of alkynes using acid chlorides as a dual carbon monoxide and carbon source. @ETH_DCHAB .

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Morandi Lab

@morandilab

2 years

Many thanks to current and former group members for their great contributions, as well as to my current ( @ETH_DCHAB @ETH_en ) and former ( @maxplanckpress ) colleagues for support! Looking forward to the new challenges ahead as full professor and head of the organic institute. Bill

D-CHAB

@ETH_DCHAB

2 years

The @ETH_en Board appointed new professors, among them Bill Morandi #LOC @ETH_DCHAB @morandilab as Full Professor of Synthetic Organic Chemistry. Karl-Heinz Altmann #IPW , Full Professor of Pharmaceutical Biology, will retire at the end of July 2022.

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Morandi Lab

@morandilab

2 years

Finally out in @NatureCatalysis - A conceptually new take on cross-coupling reactions using non-innocent electrophiles, congrats Georgios!

Non-innocent electrophiles unlock exogenous base-free coupling reactions

Nature Catalysis - Bases play a fundamental role in several iconic coupling reactions in organic chemistry but are simultaneously responsible for limitations, such as functional group tolerance....

www.nature.com

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Morandi Lab

@morandilab

1 year

We are currently (rolling process) looking for postdocs to start in late 2023 or later – please retweet. Interested? Send your application ASAP to morandi.phd @gmail .com – “postdoc 2023” in subject line

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Morandi Lab

@morandilab

3 years

Congrats to Szabo and Eric for their new azidoamination route to orthogonally functionalized diamines in @J_A_C_S ! Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalization Reaction

Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalizat...

Unprotected, primary 2-azidoamines are versatile precursors to vicinal diamines, which are among the most common motifs in biologically active compounds. Herein, we report their operationally simple...

pubs.acs.org

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Morandi Lab

@morandilab

2 years

Congrats to @BogdosMichael , @Mescerska , @AlexBismuto and Mauro for this important study revealing key factors controlling betaX/betaH selectivity in organopalladium chemistry! @NatureSynthesis @ETH_DCHAB @ChemRxiv .

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Morandi Lab

@morandilab

4 months

Congrats to Tanner Jankins @W0TangClan , Philip Blank, Andrea Brugnetti, Philip Boehm and Françoise Aouane for introducing the shuttle HAT concept for mild transfer hydrofunctionalization reactions! @ChemRxiv . #shuttlecat

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Morandi Lab

@morandilab

3 years

Congrats to @XichangDong and @JohannesRockl ! Awesome collaboration with the Waldvogel lab. Now out in @ScienceMagazine , previously on @ChemRxiv . Merging Shuttle Reactions and Paired Electrolysis: e-Shuttle Unlocks Reversible Halogenations. @ETH_DCHAB @ETH_en @ERC_Research

Jake Yeston

@JakeYeston

3 years

Shuttling pairs of Cl or Br substituents, this week in @ScienceMagazine from @morandilab and Waldvogel

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Morandi Lab

@morandilab

3 years

Many thanks to Julia and Valentina for showing the kids how exciting organic chemistry can be! #Zukunftstag @ETH_DCHAB @ETH_en

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Morandi Lab

@morandilab

9 months

Losing time drawing reaction coordinate diagrams? Check out @BogdosMichael 's solution: a web-based app for rapidly generating reaction coordinate diagrams (EveRplot): More info in the publication () and link to the app .

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Morandi Lab

@morandilab

9 months

Congrats to @aaronzhong619 , @doegger , @valentuash , @PDFinkelstein , Loris, Merlin, Nils! Introducing Skeletal Metalation to do a carbonyl-to-nickel swap in a lactam ring - unlocking some otherwise challenging molecular editing processes @NatureComms

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Morandi Lab

@morandilab

9 months

Congrats to Yannick and @origree1 on this nice collaborative work with @BhawalLab @EdinburghChem ! Ever wondered how to reversibly move a ketone along a carbon chain in a process akin to alkene chain-walking? @ETH_DCHAB

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Morandi Lab

@morandilab

2 years

RT appreciated - we are looking for a new assistant professor (tenure track) at LOC @ETH_DCHAB -amazing students, colleagues, location, school and facilities + generous long-term funding perspectives. What are you waiting for? Apply today! #chemjobs

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Morandi Lab

@morandilab

3 years

Congrats to @AlexBismuto , Patrick Müller and Patrick Finkelstein! Great collaboration with Nils Trapp and Gunnar Jeschke to develop a unifying strategy to access well-defined Ni(I)-complexes. @J_A_C_S .

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Morandi Lab

@morandilab

6 years

The group is officially moving to ETH Zürich ( @ETH_en ) on July 1st! Congrats to Bill for securing a tenured professorship along with a chair in synthetic organic chemistry. It will not be an easy task to succeed to the Diederich group but we will try our best! #realtimechem

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Morandi Lab

@morandilab

1 year

Congrats to @aaronzhong619 , @doegger , @valentuash , @PDFinkelstein , Loris, Merlin and Nils - Skeletal Metalation of Lactams through Carbonyl-to-Nickel Exchange Logic @ChemRxiv

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Morandi Lab

@morandilab

6 months

Congrats to @j_reisenbauer , @PaschkeAK , Jelena, @BenceBBotlik , @PDFinkelstein ! Single nitrogen atom insertion with unprotected indoles and pyrroles to access quinazolines and pyrimidines @JOC_OL .

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Morandi Lab

@morandilab

2 years

Congrats to @origree1 , @PDFinkelstein , @mriverocrespo , @ZurichChemist , @BogdosMichael !New research horizons for us @ETH @ETH_DCHAB - reporting @J_A_C_S highly selective CO2 sensing probes, w/ appl. in catalysis, enzymology and cell imaging w/ Leroux group.

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Morandi Lab

@morandilab

1 year

Congrats to @PDFinkelstein , Julia, @origree1 , Bence and Andri! Nitrogen atom insertion into indenes to access isoquinolines @ChemRxiv

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Morandi Lab

@morandilab

9 months

Congrats to Julia, @PDFinkelstein and Marc-Oli Ebert! Mechanistic Investigation of the Nickel-Catalyzed Transfer Hydrocyanation of Alkynes @ACSCatalysis .

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Morandi Lab

@morandilab

2 years

Congrats again to Julia Reisenbauer, @origree1 , @HappyFranchino and @PDFinkelstein ! Previously on @ChemRxiv , now final version out @ScienceMagazine .

Jake Yeston

@JakeYeston

2 years

In @ScienceMagazine this week, @morandilab slips nitrogen into indoles

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Morandi Lab

@morandilab

3 years

Congrats Tristan and Philip! Previously on @ChemRxiv , now published in @J_A_C_S . Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers.

Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers

We describe a new functional group metathesis between aryl nitriles and aryl thioethers. The catalytic system nickel/dcype is essential to achieve this fully reversible transformation in good to...

pubs.acs.org

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Morandi Lab

@morandilab

2 years

1/n Last talked to Bob in September - despite his illness he gave a virtual talk at a Summer School I was organizing and also spent 2 hours sharing stories with participating PhD students over ZOOM - just so much kindness.

Caltech Chemistry & Chemical Engineering

@CaltechCCE

2 years

The Division is saddened to report the passing of Robert Grubbs. The outpouring of memories being shared is a testament to his profound impact and influence as a professor, mentor, colleague & friend -- not only in the chemistry community, but beyond. He will be greatly missed.

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Morandi Lab

@morandilab

8 months

Congrats to @Mue11erPatrick , @PDFinkelstein for a new general route to well-defined Ni(I) species using Ni(I)-phenolate complexes! Fantastic collaboration with Nils Trapp, Gunnar Jeschke and @BismutoLab . @InorgChem .

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Morandi Lab

@morandilab

3 months

Congrats to Hendrik, Den, @origree1 , Tristan and Young Seo for their new strategy to regiodivergently access quinolinones from oxindoles. @J_A_C_S .

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Morandi Lab

@morandilab

2 years

Incredible team work by Philip, Patrick @Patrick87155410 , Miguel @mriverocrespo , Patrick @PDFinkelstein , in collaboration with Marc-Oli Ebert and Nils Trapp. Full mechanistic study giving us now a better picture of functional group metathesis

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Morandi Lab

@morandilab

4 years

Merging Shuttle Reactions and Paired Electrolysis: e-Shuttle Unlocks Reversible Halogenations - collabo with Waldvogel group, congrats @XichangDong and @johannesRockl ! 4 Rxns, no toxic Br2 or Cl2, and even direct soil remediation... @ETH_en @ETH_DCHAB

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Morandi Lab

@morandilab

6 years

Congrats to Luca, Gabri, Tristan and Suzi on their new catalytic amination reaction published in @sciencemagazine . @maxplanckpress @ETH_DCHAB @ETH_en

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Morandi Lab

@morandilab

2 years

Congrats Julia, Ben @BhawalLab and Nicola! Development of an Operationally Simple, Scalable, and HCN-Free Transfer Hydrocyanation Protocol Using an Air-Stable Nickel Precatalyst @OPRD_ACS

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Morandi Lab

@morandilab

2 years

Congrats Tristan, @Hendrik36622151 , Philip and Eric! Palladium-Catalyzed Carbothiolation of Alkenes and Alkynes for the Synthesis of Heterocycles

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Morandi Lab

@morandilab

1 year

Congrats @sevenroediger and Philip Böhm! Frustrated Ion Pair-Enabled Cross-Electrophile Coupling of Unactivated Alkyl Electrophiles | @ChemRxiv

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Morandi Lab

@morandilab

3 years

Exciting research milestone in our group thanks to @mriverocrespo and Georgios! Synthesis of recyclable porous materials through catalytic single-bond metathesis @ChemRxiv - including metal capture and heterogeneous catalysis applications. @ETH_DCHAB

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Morandi Lab

@morandilab

4 years

Congrats to Sayanti and Szabolcs on a method for the direct synthesis of unprotected sulfinamides from thiols @angew_chem !

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Morandi Lab

@morandilab

2 years

Congrats to @BogdosMichael , Olivera, Alessandro @AlexBismuto and Mauro for deriving selection rules to predict β-X vs. β-H elimination selectivity in organopalladium chemistry! Hopefully a powerful new tool for reaction design @ChemRxiv

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Morandi Lab

@morandilab

3 years

Congrats Tristan and Philip on this new exciting chapter in functional group metathesis - now swapping thioethers and cyanides! Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers

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Morandi Lab

@morandilab

1 year

Congrats to Philip and Niklas! Rhodium‐catalyzed Anti‐Markovnikov Transfer Hydroiodination of Terminal Alkynes @angew_chem .

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Morandi Lab

@morandilab

2 years

Congrats to @sevenroediger and Sebastian for a new method to diversify phosphine ligands! Nickel-catalysed diversification of phosphine ligands by formal substitution at phosphorus @ChemicalScience .

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Morandi Lab

@morandilab

2 years

Congrats to Miguel @mriverocrespo and Georgios for applying our C-S bond metathesis to the synthesis and recycling of new, versatile porous polymers - a big milestone in our reversible catalysis program @J_A_C_S @ETH_DCHAB @ETH_en @NCCR_Catalysis

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Morandi Lab

@morandilab

3 years

Congrats to Philip, Tristano, Yong Ho and Bastien! Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange

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Morandi Lab

@morandilab

3 years

A conceptually new take on cross-coupling reactions using non-innocent electrophiles by Georgios @ChemRxiv . Non-Innocent Electrophiles Unlock Exogenous Base-Free Coupling Reactions

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Morandi Lab

@morandilab

3 years

Congrats Eric and Valentina! Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C–H Amination @JOC_OL .

Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C–H Amination

We report both an intermolecular C–H amination of arenes to access N-methylanilines and an intramolecular variant for the synthesis of tetrahydroquinolines. A newly developed, highly electrophilic...

pubs.acs.org

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Morandi Lab

@morandilab

3 years

Congrats to Elliott, Yong Ho, Sven, Philip and Max for their new paper in @angew_chem . Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C–COCl Bond Cleavage

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Morandi Lab

@morandilab

6 months

Congrats to @MariusDrLutz , @sevenroediger and @mriverocrespo ! Mechanistic Investigation of the Rhodium-Catalyzed Transfer Hydroarylation Reaction Involving Reversible C–C Bond Activation @J_A_C_S .

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Morandi Lab

@morandilab

1 year

Congrats to Eric, @HappyFranchino , Teresa and Laura: Azide-Free Synthesis of N-Alkyliminophosphoranes from Phosphines and Hydroxylamine Derivatives @JOC_OL

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Morandi Lab

@morandilab

2 years

Congrats to Georgios, Gianin, Lukas, @mriverocrespo , and @Hendrik36622151 ! Pd-Catalyzed Direct Deoxygenative Arylation of Non-π-Extended Benzyl Alcohols with Boronic Acids via Transient Formation of Non-Innocent Isoureas

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Morandi Lab

@morandilab

2 years

Congrats to Sven @sevenroediger and Sebastian! A novel catalytic method to diversify phosphine ligands through formal aryl/alkyl swap. @ChemRxiv

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Morandi Lab

@morandilab

4 years

Congrats to our team of @HartwigGroup Alumni (Philip, Sven and @AlexBismuto ) for their Palladium‐catalyzed Chlorocarbonylation of Aryl (pseudo)Halides through in situ Generation of Carbon Monoxide

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Morandi Lab

@morandilab

1 year

Congrats to @XichangDong and our collaborators from the Waldvogel group! Controlling Selectivity in Shuttle Hetero‐difunctionalization Reactions: Electrochemical Transfer Halo‐thiolation of Alkynes @angew_chem !

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Morandi Lab

@morandilab

1 year

Congrats @PDFinkelstein , Julia, @BenceBBotlik , @origree1 and Andri - Nitrogen atom insertion into indenes to access isoquinolines - now published in Chemical Science

Nitrogen atom insertion into indenes to access isoquinolines

We report a convenient protocol for a nitrogen atom insertion into indenes to afford isoquinolines. The reaction uses a combination of commercially available phenyliodine(iii) diacetate (PIDA) and...

pubs.rsc.org

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Morandi Lab

@morandilab

3 years

Congrats to Bill for starting as an Associate Editor for @OrgChemFront from the @RoySocChem . With an IF of 5.2 and a rapid turnover, @OrgChemFront is an excellent venue for rapid publication of your key findings in organic chemistry

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Morandi Lab

@morandilab

11 months

Congrats to Giedre, Celine, @Mue11erPatrick and Aurelio - a new method to use nitroarenes as aryl nitrene precursors for sp3 C-H amination!

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Morandi Lab

@morandilab

3 years

Congrats to Elliott, Yong Ho, Sven, Philip and @FontourM for this great collaborative work! Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C–COCl Bond Cleavage - now on @ChemRxiv

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Morandi Lab

@morandilab

3 years

Congrats Yong Ho and Elliott for this mind-bending CO shuffling process published in @J_A_C_S ! Modular Cyclopentenone Synthesis through the Catalytic Molecular Shuffling of Unsaturated Acid Chlorides and Alkynes

Modular Cyclopentenone Synthesis through the Catalytic Molecular Shuffling of Unsaturated Acid...

We describe a general strategy for the intermolecular synthesis of polysubstituted cyclopentenones using palladium catalysis. Overall, this reaction is achieved via a molecular shuffling process...

pubs.acs.org

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Morandi Lab

@morandilab

1 year

Congrats to @BogdosMichael and @Mue11erPatrick ! Structural Evidence for Aromatic Heterocycle N–O Bond Activation via Oxidative Addition @ChemRxiv

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Morandi Lab

@morandilab

6 months

Congrats to Chad, Egor, @doegger , Philipp, as well as Quentin and Thomas from @SpiroChemAG ! Reactivity and Selectivity of Azaspirocycles in Radical C–H Functionalization @JOC_OL - special issue on academia/industry collaborations. @Innosuisse .

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Morandi Lab

@morandilab

3 years

Many congrats to our former colleague @ben_list and the whole @ListLaboratory from @maxplanckpress , as well as @dmac68 and the whole @MacMillan_Lab !

The Nobel Prize

@NobelPrize

3 years

BREAKING NEWS: The 2021 #NobelPrize in Chemistry has been awarded to Benjamin List and David W.C. MacMillan “for the development of asymmetric organocatalysis.”

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Morandi Lab

@morandilab

2 years

A warm welcome to our new postdoc Tanner Jankins @W0TangClan joining us from @scrippsresearch @EngleLab !

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Morandi Lab

@morandilab

4 years

We have just published on @ChemRxiv a rare example of catalytic reversible transfer reaction exhibiting high selectivity for the kinetic product! Congrats Ben, Julia and Christian for this selective hydrocyanation

ChemRxiv

@ChemRxiv

4 years

Overcoming Selectivity Issues in Reversible Catalysis – A Transfer Hydrocyanation Exhibiting High Kinetic Control by Bill Morandi & co-workers

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Morandi Lab

@morandilab

3 years

Congrats to Lin, @AlexBismuto , Simon and Nils for the development of a promising new manifold for alkane dehydrogenation in @angew_chem ! Ru‐catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism

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Morandi Lab

@morandilab

3 years

Many congratulations to our postdoc Dr. Alessandro Bismuto @AlexBismuto for starting his independent academic career @uniGoettingen in November!

Alessandro Bismuto

@AlexBismuto

3 years

I am very excited to announce that this November I will start my research group @uniGoettingen funded by the generous Liebig Fellowship of the FCI @chemieverband #NewPI #academiclife

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@morandilab

3 years

Many congratulations to our former postdoc Dr. Benjamin Bhawal for starting his independent academic career as a Christina Miller Fellow @EdinburghChem . Follow him @BhawalLab for exciting research and opportunities

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Morandi Lab

@morandilab

4 years

Congrats to Eric, Szabolcs, Tristan and Laura for developing scalable routes to new, substituted aminating reagents for alkene aminofunctionalization in @angew_chem . Dedicated to the memory of Kilian @GroupMuniz , a true pioneer in this area.

Design and Scalable Synthesis of N‐Alkylhydroxylamine Reagents for the Direct Iron‐Catalyzed...

The direct synthesis of unprotected secondary and tertiary alkylamines from alkenes is reported. Aminative difunctionalization was mediated by an iron catalyst to yield a family of ten hydroxylamin...

onlinelibrary.wiley.com

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Morandi Lab

@morandilab

5 years

Awesome group retreat in Oberwallis last week! Unfortunately our colleagues @ETH_en forecast a gloomy future for the #AletschGlacier , and this picture we took last week will not be possible anymore by 2100 #globalwarming

ETH Zurich

@ETH_en

5 years

The largest #glacier in the Alps is visibly suffering the effects of #globalwarming . ETH researchers have now calculated how much of the #AletschGlacier will still be visible by the end of the century.

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Morandi Lab

@morandilab

1 year

Congrats to Giedre and Julia! Deaminative coupling of benzylamines and arylboronic acids - now published in Chemical Science

Deaminative coupling of benzylamines and arylboronic acids

A metal-free deaminative coupling of non-prefunctionalised benzylamines and arylboronic acids is reported. In this operationally simple reaction, a primary amine in benzylamine is converted into a...

pubs.rsc.org

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Morandi Lab

@morandilab

4 years

Congrats to @ZurichChemist and Valentina for their " transfer hydrocarbylation" paralleling the well-known transfer hydrogenation! Shuttle Arylation by Rh(I) Catalyzed Reversible Carbon–Carbon Bond Activation of Unstrained Alcohols

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Morandi Lab

@morandilab

6 years

We finally have our new ETH website! Thanks Marius!

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Morandi Lab

@morandilab

4 years

The amination team strikes again! A range of novel aminating reagents for secondary and tertiary aminations, including medicinally relevant groups. @ChemRxiv via @figshare

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Morandi Lab

@morandilab

5 years

Rare footage of Bill being delivered by cargobike to @uni_copenhagen for his talk. @TheLeeLab_Chem @PittelkowLab #greathospitality

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Morandi Lab

@morandilab

4 years

Do you need a practical and direct route to make orthogonally functionalized diamines from alkenes? Thanks to the new Fe-catalyzed synthesis of unprotected azidoamines developed by Szabo and Eric this is now easier! @ChemRxiv via @figshare

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Morandi Lab

@morandilab

6 years

Check out this @NatureChemistry News and Views article by Yong Ho and the Boss highlighting an awesome carbonylation paper from the Arndtsen group! "In situ acyl triflates ace it"

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@morandilab

3 years

Congratulations to @ZurichChemist and Valentina for their publication in @Chem_CP ! A catalytic transfer hydrocarbylation paralleling the well-known transfer hydrogenation!

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Morandi Lab

@morandilab

4 years

Congrats to Tristan, @AlexBismuto and Zhong! Highlights of the paper: highly active Ni catalyst for macrocycles synthesis through ring-closing thioether metathesis AND detailed organometallic studies supporting a Ni(0)/Ni(II) mechanism.

Angewandte Chemie

@angew_chem

4 years

Nickel-Catalyzed Inter- and Intramolecular Aryl Thioether Metathesis by Reversible Arylation (Morandi)

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Morandi Lab

@morandilab

4 years

An exceptional teacher, mentor and scientist. But more importantly, a wonderful human being and outstanding colleague. You will be sorely missed by everyone. RIP. #chemistrylegend

Chemistry Europe

@ChemEurope

4 years

It is with profound sadness that we announce that our Chemistry Europe Fellow François Diedrich passed away.

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Morandi Lab

@morandilab

3 years

Congrats Suzanne, Georgios and Julia! A Site-selective and Stereospecific Cascade Suzuki-Miyaura Annulation of Alkyl 1,2-Bisboronic Esters and 2,2’-Dihalo 1,1’-Biaryls - now published @ChemCommun .

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Morandi Lab

@morandilab

1 year

Congrats to Philip, Elliott and Joel for an Intermolecular Pauson–Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate @JOC_OL

Intermolecular Pauson–Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate

A strategy for the palladium-catalyzed intermolecular synthesis of polysubstituted cyclopentenones is reported. The three-component reaction utilizes vinyl iodides and internal alkynes to form the...

pubs.acs.org

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Morandi Lab

@morandilab

1 year

Congrats Georgios and Loélie! Catalytic disproportionation via carbonate redox tags – a unified strategy for mild hydrogenolysis and oxidation of C–O bonds @ChemRxiv

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Morandi Lab

@morandilab

3 years

Many congratulations to our former PhD student Yong Ho Lee for starting his own lab as an Assistant Professor at Korea University! Please make sure to follow his group @yoleelab and for exciting research and job opportunities!

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@morandilab

3 years

Congrats to Tristan and Adrian for their manuscript in Organic Letters @JOC_OL . Nickel-Catalyzed Cyanation of Aryl Thioethers

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Morandi Lab

@morandilab

1 year

Congrats to Georgios and Loélie - the final version of their paper - Ni-catalyzed mild hydrogenolysis and oxidations of C–O bonds via carbonate redox tags - has now appeared in @NatureComms - .

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Morandi Lab

@morandilab

4 years

Benjamin, Julia and Christian publish today in @J_A_C_S their kinetically controlled hydrocyanation, showing the path for selectivity control in reversible catalysis! Originally reported on @ChemRxiv

Overcoming Selectivity Issues in Reversible Catalysis: A Transfer Hydrocyanation Exhibiting High...

Reversible catalytic reactions operate under thermodynamic control, and thus, establishing a selective catalytic system poses a considerable challenge. Herein, we report a reversible transfer...

pubs.acs.org

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Morandi Lab

@morandilab

5 years

Simply mind-blowing! Congrats to our former colleagues @CornellaLab for a real breakthrough in homogeneous catalysis

Cornellab

@CornellaLab

5 years

High-valent Bismuth Redox Catalysis unlocked. Now in @ChemRxiv :

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Morandi Lab

@morandilab

2 years

Congrats Aaron @aaronzhong619 on this news and views article published in @NatureSynthesis highlighting some elegant work from the @TheLautensGroup .

Carbon–carbon bond formation in reverse

Nature Synthesis - The reversible formation of carbon–carbon bonds is key in many catalytic reactions but its mechanism is challenging to study. Now, a detailed investigation into a...

www.nature.com

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Morandi Lab

@morandilab

6 years

Congrats Yong Ho - introducing catalytic functional group metathesis @ETH_DCHAB @ETH_en @maxplanckpress Congrats as well to the Arndtsen group for their independent discovery of a very similar reaction (DOI: 10.1021/jacs.8b06605)!

Metathesis-active ligands enable a catalytic functional group metathesis between aroyl chlorides...

Nature Chemistry - Functional group interconversion typically requires reactive reagents to irreversibly generate a desired product in high yield and selectivity. Now, a CO-free catalytic...

www.nature.com

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Morandi Lab

@morandilab

3 years

A warm welcome to our new postdocs - Allegra Franchino @HappyFranchino , previously @dixon_group and @Echavarren_Lab - Hongyu Zhong @aaronzhong619 , previously @ChirikGroup - Chad Ungarean, previously @SarlahLab - Egor Larin, previously @TheLautensGroup .

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Morandi Lab

@morandilab

4 years

Congrats to @ZurichChemist for our first Chem Rev, part of a special issue on selective C-C cleavage. Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols

Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols

The functionalization of molecules by cleaving inert carbon–carbon single bonds is regarded as a great synthetic challenge due to their inherent stability. In recent years, significant progress has...

pubs.acs.org

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Morandi Lab

@morandilab

3 years

Congrats to our two PhD students Julia Reisenbauer and @ZurichChemist for securing, respectively, a Best Poster Award at the Swiss Summer School 2021 and a Runner-Up Best Oral Presentation Award at the SCS Fall Meeting 2021 @SwissChemistry

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Morandi Lab

@morandilab

8 months

Congrats to Elliott, Minyoung and our new colleague Tae-Lim Choi for a fantastic collaboration. Ever wanted two different functional groups in your polynorbornenes? Now you can! @MacroJnls_ACS

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Morandi Lab

@morandilab

4 years

Ever wondered if Hydroformylation could be turned into a process where two new C-C bonds are forged concomitantly instead of one? Yong Ho and Elliott now report a Palladium-Catalyzed Carboformylation Enabled by a Molecular Shuffling Process via @figshare

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Morandi Lab

@morandilab

4 years

Congrats @AlexBismuto , Tristan and Patrick for this new reaction including a detailed mechanistic study (kinetics + stoichiometric exps)! Nickel-catalyzed Amination of Aryl Thioethers: A Combined Synthetic and Mechanistic Study

Nickel-Catalyzed Amination of Aryl Thioethers: A Combined Synthetic and Mechanistic Study

Herein, we report a nickel–1,2-bis(dicyclohexylphosphino)ethane (dcype) complex for the catalytic Buchwald–Hartwig amination of aryl thioethers. The protocol shows broad applicability with a variety...

pubs.acs.org

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Morandi Lab

@morandilab

2 years

Many thanks to @TheLautensGroup and his team for highlighting two of our recent publications (thioether annulation and phosphine ligand derivatization) in #Synfacts @thiemechemistry . 😀Please check and

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Morandi Lab

@morandilab

3 years

Want more information about our recent carboformylation in @NatureChemistry ? check this perspective from @ArndtsenBruce lab: . Elliott also wrote an excellent "behind the paper" article:

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Morandi Lab

@morandilab

2 years

Congrats again Pep @CornellaLab !

Organometallics

@Orgmet_ACS

2 years

Too bad the @Orgmet_ACS Distinguished Author Award Symposium here at #ACSFall2022 must come to an end.* Congrats again to Pep Cornella @CornellaLab and thanks to our speakers for a fantastic day of great science @ACSINORDivision @ACSorganic @ACSPublications

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Morandi Lab

@morandilab

2 years

Congrats to the whole team - fantastic multidisciplinary collaboration with Prof. Neese and DeBeer led by our former postdoc Sayanti Chatterjee to unravel the complex mechanism of our previously reported Fe-catalyzed aminohydroxylation reaction

J. Am. Chem. Soc.

@J_A_C_S

2 years

A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant” @mpicec_press #Iron #Aminofunctionalization #Olefins

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Morandi Lab

@morandilab

6 years

Congrats to Tobias, Szabo and Zhong on their nice metathesis reaction of ethers in @angew_chem .

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Morandi Lab

@morandilab

5 years

Pls RT - We are looking to make a senior hire in the area of chemical biology! @ETH_en offers top facilities, a stable funding situation, outstanding students, and great colleagues in a cosmopolitan city with unmatched quality of life

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Morandi Lab

@morandilab

2 years

Congrats to our brilliant postdoc @HappyFranchino for starting her own lab as an Assistant Professor at @DurhamChemistry in the Fall!

Allegra Franchino

@HappyFranchino

2 years

I am over the moon to announce that I will start as an Assistant Professor at @DurhamChemistry in September. A huge thank you to my advisors @dixon_group , @Echavarren_Lab and @Morandilab , and to Durham for having me! A PhD advert (all nationalities) will follow soon.

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Morandi Lab

@morandilab

5 years

Bill's ETH inaugural lecture is now accessible online: . @ETH_en @ETH_DCHAB

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Morandi Lab

@morandilab

7 years

Our research on shuttle catalysis and metathesis will be funded by the ERC! #ERCStG #RealTimeChem

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